Volume 43, Issue 3
Chin. J. Struct. Chem. 第3期共收录9篇文章(1篇News & Views，5篇Article，3篇Review)，内容涉及水系电池、CO2催化、发光材料、钙钛矿太阳能电池和气体传感MOF等。
感谢作者、编委与审稿专家的大力支持。敬请各位专家和同行阅读分享与批评指正！
2024年开始，CJSC文章可在Elsevier网站免费阅读下载全文。
封面文章
中山大学余丁山教授 & 广西大学朱园勤教授研究论文——Long-lifespan aqueous alkaline and acidic batteries enabled by redox conjugated covalent organic polymer anodes
在本期封面文章中，中山大学余丁山教授课题组与广西大学朱园勤教授课题组合作，构筑了一种兼具氧化还原活性、超亲水性和宽pH适应性的共价有机聚合物(COP) 作为酸性和碱性水系电池的长寿命负极材料。传统无机负极材料难以同时具备对酸性和碱性电解液的耐受性，且在反应过程中易产生溶解、腐蚀或枝晶等问题，严重制约了电池循环寿命的提升。COP的无定形交联网络和扩展共轭结构能够赋予其畅通的离子和电子传输通道以及优异的酸碱共耐受性，因此展现出了快速的表面控制氧化还原反应动力学以及在单电极和全电池体系中一致的超高稳定性。该项研究为用于酸性和碱性水系电池的高性能和长寿命聚合物电极的结构设计和实际应用提供了理论指导。
1
News & Views
Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction
Yufei Jia, Fei Li, Ke Fan*
Chin. J. Struct. Chem., 2024, 43, 100255
☑ An amphoteric metal-doped nano-octahedron electrocatalysts with abundant bimetallic sites exhibit excellent activity and selectivity in converting CO2 to C2+ products.
☑ 一种新的两性金属掺杂纳米八面体电催化剂具有丰富的双金属位点，在将 CO2 转化为 C2+ 产物方面表现出卓越的活性和选择性。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100255
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02
Article
A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting
Kun Zhang, Ni Dan, Dan-Dan Ren, Ruo-Yu Zhang, Xiaoyan Lu, Ya-Pan Wu*, Li-Lei Zhang*, Hong-Ru Fu*, Dong-Sheng Li
Chin. J. Struct. Chem., 2024, 43, 100244
☑ A simple donor-acceptor (D-A) molecule, 9-(1H-benzotriazol-1-ylmethyl)-9H-carbazole (CzBtrz) shows the superhigh heat-resisting phosphorescence property with a ambient lifetime of 988.54 ms at 545 nm, the phosphorescence performance can maintain stability in a large temperature region from 77 to 350 K (ΔT = 273 °C), exceeding those of other room-temperature phosphorescence (RTP) systems, and it exhibits the white light via thermally activated delayed fluorescence and phosphorescence dual emission.
☑ 一种简单的供体-受体 (D-A) 分子9-(1H-苯并三唑-1-基甲基)-9H-咔唑 (CzBtrz) 显示出超高耐热磷光特性，在 545 nm 波长下的寿命为 988.54 ms。其磷光性能可在 77 至 350 K (ΔT = 273 ℃) 的较大温度范围内保持稳定，超过了其他室温磷光 (RTP) 系统，且热激发后能产生延迟荧光和磷光双发射呈现白光。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100244
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03
Article
Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction
Ziruo Zhou, Wenyu Guo, Tingyu Yang, Dandan Zheng*, Yuanxing Fang, Xiahui Lin*, Yidong Hou, Guigang Zhang, Sibo Wang*
Chin. J. Struct. Chem., 2024, 43, 100245
☑ The 2-aminopyridine molecule with the strong electron-withdrawing group is fused into the skeleton edge of carbon nitride layers to render the material with extended light absorption, appropriate nitrogen defects, and ultrathin nanosheet structure for improved CO2 reduction performance by visible light.
☑ 将氮化碳层的骨架边缘经强拉电子能力的2-氨基吡啶基团修饰，使材料具有更强的光吸收能力、适当的氮缺陷和超薄的纳米片结构，从而提高了可见光的二氧化碳还原性能。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100245
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04
Article
Long-lifespan aqueous alkaline and acidic batteries enabled by redox conjugated covalent organic polymer anodes
Yuanzhe Lu, Yuanqin Zhu*, Linfeng Zhong*, Dingshan Yu*
Chin. J. Struct. Chem., 2024, 43, 100249
☑ A redox conjugated covalent organic polymer (p-HATN) was explored as a superhydrophilic and wide pH adaptable anode for robust aqueous alkaline and acidic batteries, which displays long cycle life—surpassing most previously reported systems.
☑ 该项工作将氧化还原共价有机聚合物p-HATN作为一种超亲水性、pH 值适应性强的阳极，用于耐用的水性碱性和酸性电池，其循环寿命超越了之前报道的大多数系统。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100249
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05
Article
Te-doped Fe3O4 flower enabling low overpotential cycling of Li−CO2 batteries at high current density
Huyi Yu, Renshu Huang, Qian Liu, Xingfa Chen, Tianqi Yu, Haiquan Wang, Xincheng Liang, Shibin Yin*
Chin. J. Struct. Chem., 2024, 43, 100253
☑ Te-doped Fe3O4 is used as the cathode catalyst of LCBs, which inhibits the disproportionation of C2O42− through the electron transfer from Te to O.
☑ 该工作将Te掺杂Fe3O4用作LCB的阴极催化剂，通过Te向O的电子转移抑制了 C2O42- 的歧化。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100253
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06
Article
New thermoelectric semiconductors Pb5Sb12+xBi6−xSe32 with ultralow thermal conductivity
Ruizhi Yang, Xia Li, Weiping Guo, Zixuan Chen, Hongwei Ming, Zhong-Zhen Luo*, Zhigang Zou
Chin. J. Struct. Chem., 2024, 43, 100268
☑ Five new pavonite-type Pb5Sb12+xBi6−xSe32 with a quasi-two-dimensional layered structure have been reported, exhibiting an ultralow lattice thermal conductivity due to their intricate composition and anisotropic crystal structure.
☑ 该工作报道了五种具有准二维层状结构的新型辉锑矿型化合物Pb5Sb12+xBi6−xSe32，复杂的化学组成和各向异性的晶体结构使其表现出超低的晶格热导率。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100268
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07
Review
MicroED as a powerful technique for the structure determination of complex porous materials
Chao Ma, Cong Lin*, Jian Li*
Chin. J. Struct. Chem., 2024, 43, 100209
☑ The innovative and pivotal MicroED technique can overcome the difficulties of conventional SCXRD and PXRD in the structure determination of complex porous materials encompassing zeolites, MOFs, and COFs, enabling the efficient and precise understanding of their atomic structures and intrinsic structure-property relationship.
☑ 在对包括沸石、MOFs和COFs在内的复杂多孔材料进行结构表征时，新兴的MicroED 技术可以突破传统单晶衍射和粉末衍射的限制，从而高效而精确地研究其原子结构和内在的结构-性能关系。
原文链接
https://doi.org/10.1016/j.cjsc.2023.100209
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08
Review
Advancement in porphyrin/phthalocyanine compounds-based perovskite solar cells
Chen Lu, Zefeng Yu, Jing Cao*
Chin. J. Struct. Chem., 2024, 43, 100240
☑ This review discusses significant progress made in enhancing the performance of perovskite solar cells (PSC) through the doping of porphyrin and phthalocyanine compounds. These macrocyclic compounds contribute to regulating the properties of perovskite films, significantly improving charge transfer efficiency, and enhancing device stability. The review emphasizes their role in passivating defects, preventing ion migration, and facilitating charge transfer, underscoring their potential to expand the application range of PSCs.
☑ 该综述讨论了通过掺杂卟啉和酞菁化合物在提高钙钛矿太阳能电池（PSC）性能方面取得的重大进展。这些大环化合物有助于调节钙钛矿薄膜的特性，显著提高电荷转移效率并增强器件稳定性。文中亦讨论了这类化合物在钝化缺陷、防止离子迁移和促进电荷转移方面的作用，肯定了其在PSC应用方面的潜力。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100240
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09
Review
Gas sensors based on metal-organic frameworks: Challenges and opportunities
Xiaoyan Peng, Xuanhao Wu, Fan Yang, Yefei Tian, Mingming Zhang, Hongye Yuan*
Chin. J. Struct. Chem., 2024, 43, 100251
☑ This min-review summarizes recent advances in the structural design of MOFs for gas sensing, their integration with electronic devices, and the combination of sensing with artificial intelligence. Current challenges and opportunities for the ongoing pursuit of miniaturization and building of smart sensing systems with anomaly detection, self-calibration, and lifetime prediction are also included.
☑ 该综述总结了用于气体传感的 MOF 结构设计、MOF 与电子设备的集成以及传感与人工智能的结合等方面的最新进展，并展望了其在追求微型化和构建具有异常检测、自我校准和寿命预测功能的智能传感系统方面所面临的挑战和机遇。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100251
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