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Chin. J. Struct. Chem. 第11期共收录12篇文章。报道了MOF、COF、纳米团簇结构、分子筛等结构与性能相关的工作。
感谢作者、编委与审稿专家的大力支持。敬请各位专家和同行阅读分享与批评指正！
CJSC文章可在Elsevier网站下载全文。
Volume 43, Issue 11
封面文章
福州大学林森教授等人——Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction
在本期封面文章中，福州大学林森教授等人通过氮原子掺杂，对负载于缺陷石墨烯上的铜单原子催化剂 (Cu SACs) 的配位环境予以调控，并探究了其表面二氧化碳还原反应 (CO2RR) 的电催化性能。其中，氮原子在次配位层掺杂的三配位Cu SACs具有适中的*CO 结合强度，能有效实现CO2电还原为甲烷、甲醇等深度还原产物。该研究有利于深入理解CO2RR在单原子催化剂上的反应机理，还为设计高效的CO2深度还原单原子催化剂提供了思路。
01
News & Views
The electrolyte solvation and interfacial chemistry for anode-free sodium metal batteries
Haiying Lu, Weijie Li*
Chin. J. Struct. Chem., 2024, 43, 100334
原文链接
https://doi.org/10.1016/j.cjsc.2024.100334
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02
News & Views
Lowering the kinetic barrier via enhancing electrophilicity of surface oxygen to boost acidic oxygen evolution reaction
Ling Tang, Yan Wan, Yangming Lin*
Chin. J. Struct. Chem., 2024, 43, 100345
原文链接
https://doi.org/10.1016/j.cjsc.2024.100345
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03
News & Views
A flexible-robust MOF for efficient purification of perfluoropropane
Lixian Cai, Yingxiang Ye*
Chin. J. Struct. Chem., 2024, 43, 100368
原文链接
https://doi.org/10.1016/j.cjsc.2024.100368
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04
News & Views
Anion-pillared MOFs for challenging hydrocarbon separations
Yunjia Jiang, Lingyao Wang, Yuanbin Zhang*
Chin. J. Struct. Chem., 2024, 43, 100374
原文链接
https://doi.org/10.1016/j.cjsc.2024.100374
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05
Highlights
Shining bright: Revolutionary near-unity NIR phosphorescent metal nanoclusters
Rakesh Kumar Gupta, Zhi Wang, Di Sun*
Chin. J. Struct. Chem., 2024, 43, 100417
原文链接
https://doi.org/10.1016/j.cjsc.2024.100417
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06
Perspective
Nanomaterials with highly ordered nanostructures: Definition, influence and future challenge
Ningxiang Wu, Huaping Zhao, Yong Lei*
Chin. J. Struct. Chem., 2024, 43, 100392
原文链接
https://doi.org/10.1016/j.cjsc.2024.100392
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07
Article
Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction
Yuxiang Zhang, Jia Zhao, Sen Lin*
Chin. J. Struct. Chem., 2024, 43, 100415
☑ Doping nitrogen atom in the second coordination shell of single-atom catalysts can regulate the catalytic selectivity of CO2RR.
☑ 氮原子在单原子催化剂的第二配位壳层中的掺杂可以调节 CO2RR 的催化选择性。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100415
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08
Article
Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction
Liang Ma, Zhou Li, Zhiqiang Jiang, Xiaofeng Wu*, Shixin Chang, Sónia A.C. Carabineiro*, Kangle Lv*
Chin. J. Struct. Chem., 2024, 43, 100416
☑ This study highlights the importance of precursors (urea, dicyandiamide and melamine) on the photocatalytic performance of g-C3N4. UCN exhibits the highest photocatalytic activity among three g-C3N4 samples for NO oxidation and CO2 reduction.
☑ 这项研究强调了前驱体 (尿素、双氰胺和三聚氰胺) 对 g-C3N4 光催化性能的重要性。在氧化 NO 和还原 CO2 的过程中，UCN 在三种 g-C3N4 样品中表现出最高的光催化活性。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100416
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09
Article
Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite
Zhuoer Cai, Yinan Zhang, Xiu-Ni Hua*, Baiwang Sun*
Chin. J. Struct. Chem., 2024, 43, 100426
☑ Order-disorder motion of organic cations appears in a stable layered two-dimensional perovskite, featuring dielectric response and stable sandwich structure.
☑ 有机阳离子的有序-无序运动出现在稳定的层状二维过氧化物中，具有介电响应和稳定的夹层结构。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100426
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10
Review
Design of two-dimensional porous covalent organic framework semiconductors for visible-light-driven overall water splitting: A theoretical perspective
Yuting Wu, Haifeng Lv*, Xiaojun Wu*
Chin. J. Struct. Chem., 2024, 43, 100375
☑ Two-dimensional (2D) COFs hold great promise as photocatalysts for overall water splitting due to their rich physical properties and active sites. This mini-review emphasizes the design principle of 2D COFs for photocatalytic overall water splitting and discusses the challenges and potential in practical application from a theoretical perspective.
☑ 二维 (2D) COF 因其丰富的物理性质和活性位点而有望成为整体水分离的光催化剂。这篇微型综述强调了二维 COF 光催化整体水分离的设计原理，并从理论角度探讨了实际应用中的挑战和潜力。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100375
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11
Review
Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement
Ziyi Liu, Xunying Liu, Lubing Qin, Haozheng Chen, Ruikai Li, Zhenghua Tang*
Chin. J. Struct. Chem., 2024, 43, 100405
☑ This review summarizes the recent advances of employing alkynyl ligand to prepare atomically precise metal nanoclusters, and some critical thoughts on future outlooks are also proposed.
☑ 本综述总结了利用炔基配体制备原子精密金属纳米团簇的最新进展，并对未来前景提出了一些重要思考。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100405
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12
Review
A minireview to ketene chemistry in zeolite catalysis
Wei Chen, Pieter Cnudde*
Chin. J. Struct. Chem., 2024, 43, 100412
☑ Ketenes play a crucial role in zeolite catalysis and C1 chemistry, forming intermediates for various reactions. Their stability, mobility, and activity are influenced by zeolite topologies and acidities.
☑ 烯酮在沸石催化和 C1 化学中发挥着重要作用，是各种反应的中间体。它们的稳定性、流动性和活性受到沸石拓扑结构和酸度的影响。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100412
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往期回顾
2024年第10期目录
2024年第9期目录
2024年第8期目录
2024年第7期目录
2024年第6期目录
