Chin. J. Struct. Chem. 2024年第10期目录

Chin. J. Struct. Chem. 第10期共收录14篇文章。内容涉及全固态电池、分子筛、一维混合铅卤化物、氮化碳薄膜及Cu₂₈纳米簇等结构与功能！

感谢作者、编委与审稿专家的大力支持。敬请各位专家和同行阅读分享与批评指正！

CJSC文章可在Elsevier网站下载全文。

封面文章

原文链接

https://doi.org/10.1016/j.cjsc.2024.100322

原文链接

https://doi.org/10.1016/j.cjsc.2024.100325

原文链接

https://doi.org/10.1016/j.cjsc.2024.100329

原文链接

https://doi.org/10.1016/j.cjsc.2024.100330

原文链接

https://doi.org/10.1016/j.cjsc.2024.100331

原文链接

https://doi.org/10.1016/j.cjsc.2024.100344

原文链接

https://doi.org/10.1016/j.cjsc.2024.100393

09

Article

Electrostatically driven kinetic inverse CO₂/C₂H₂ separation in LTA-type zeolites 

Yongheng Ren, Yang Chen, Hongwei Chen, Lu Zhang, Jiangfeng Yang, Qi Shi, Lin-Bing Sun, Jinping Li, Libo Li*

Chin. J. Struct. Chem., 2024, 43, 100394

☑ K-ion modulation of zeolite 5A creates a compact pore space matching CO₂ and C₂H₂, which restricts the molecular orientation into pore channels and enhances the charge recognition effect, thereby increasing the kinetic diffusion difference between the two gas components and achieving inverse CO₂/C₂H₂ separation.  

☑ 本文采用钾离子调控5A分子筛，形成与CO₂和C₂H₂相匹配的致密孔隙空间，限制分子取向进入孔道，增强电荷识别作用，从而增大两种气体组分之间的动力学扩散差异，实现 CO₂/C₂H₂的逆向分离。

10

Article

Temperature- and pressure-responsive photoluminescence in a 1D hybrid lead halide

Huan Hu, Ying Zhang, Shi-Shuang Huang, Zhi-Gang Li, Yungui Liu, Rui Feng*, Wei Li*

Chin. J. Struct. Chem., 2024, 43, 100395

☑ The temperature- and pressure-responsive emission of a new one-dimensional hybrid lead halide CyPbBr₃ (Cy = cytosine cation) was studied. Its broadband feature is attributed to the strong electron-phonon coupling while its 4.5-fold pressure-induced emission enhancement rises from the pressure suppressed non-radiative energy loss. 

☑  本文制备了一种新型一维混合铅卤化物CyPbBr₃ (Cy = 胞嘧啶阳离子)，并测试了其温度和压力响应的发射性能。该材料宽带发射特性可归因于强电子-声子耦合，而其压力诱导发射增强4.5倍则源于压力抑制的非辐射能量损失。

11

Article

[Cs₁₄Cl][Tm₇₁Se₁₁₀]: An unusual salt-inclusion chalcogenide containing different valent Tm centers and ultralow thermal conductivity

Hong Chen, Mao-Yin Ran, Long-Hua Li*, Xin-Tao Wu, Hua Lin*

Chin. J. Struct. Chem., 2024, 43, 100397

☑ Combining different structural motifs leads to an unprecedented salt-inclusion chalcogenide [Cs₁₄Cl][Tm₇₁Se₁₁₀] which exhibits ultralow thermal conductivity of 0.29–0.24 W/m·K at 300–673 K. 

12

Article

Dynamic photoluminescence switching of carbon nitride thin films for anticounterfeiting and encryption

Hang Meng, Bicheng Zhu, Ruolun Sun, Zixuan Liu, Shaowen Cao*, Kan Zhang, Jiaguo Yu, Jingsan Xu*

Chin. J. Struct. Chem., 2024, 43, 100410

☑ This work introduces the thermal vapor deposition of carbon nitride (CN) thin films featuring unique dynamic photolumine-scence (PL) switching properties. After LED illumination, the PL intensity of the film increases and then fades in darkness. We developed an advanced luminescent device for secure encrypted information transmission, readable with a UV lamp and erasable with a portable LED, preventing information leakage. 

13

Review

Ligand effects on geometric structures and catalytic activities of atomically precise copper nanoclusters

Luyao Lu, Chen Zhu, Fei Li, Pu Wang*, Xi Kang*, Yong Pei*, Manzhou Zhu* 

Chin. J. Struct. Chem., 2024, 43, 100411

☑  This work demonstrates the ligand effects on geometric structures and catalytic activities based on two Cu₂₈ structure-related nanoclusters. 

14

Review

Cathodal Li-ion interfacial transport in sulfide-based all-solid-state batteries: Challenges and improvement strategies

Yue Zheng, Tianpeng Huang, Pengxian Han, Jun Ma*, Guanglei Cui*

Chin. J. Struct. Chem., 2024, 43, 100390

☑  Scientific advances and open questions in understanding and solving the cathodal Li-ion interfacial transport issues on atomic, micro-mesoscopic, and macroscopic scales in sulfide-based all-solid-state batteries are summarized and discussed.