Chin. J. Struct. Chem. 2024年第9期目录

Chin. J. Struct. Chem. 第9期共收录14篇文章。内容涉及传感器、室温磷光、镧系发光材料、沸石结构调控、OLED以及有机无机杂化钙钛矿材料等。

感谢作者、编委与审稿专家的大力支持。敬请各位专家和同行阅读分享与批评指正！

CJSC文章可在Elsevier网站下载全文。

封面文章

原文链接

https://doi.org/10.1016/j.cjsc.2024.100357

原文链接

https://doi.org/10.1016/j.cjsc.2024.100371

原文链接

https://doi.org/10.1016/j.cjsc.2024.100372

原文链接

https://doi.org/10.1016/j.cjsc.2024.100369

原文链接

https://doi.org/10.1016/j.cjsc.2024.100391

原文链接

https://doi.org/10.1016/j.cjsc.2024.100356

原文链接

https://doi.org/10.1016/j.cjsc.2024.100335

09

Article

Toward the microporous zeolite family with tunable large-medium cage and pore opening 

Zhenzhen Zhao, Meichen Jiao, Jiejie Ling, Han Jiang, Yan Gao, Hao Xu, Hai-Qing Li, Jingang Jiang*, Peng Wu*, Le Xu*

Chin. J. Struct. Chem., 2024, 43, 100336

☑ (Si,Ge)-IWV and (Si,Ge,Al)-IWV (large pore and supercage) zeolites were hydrothermally prepared, and the post-synthetic treatment led to the formation of (Si,Ge)-NES zeolite (medium pore and cage). IWV zeolite with only Ge and Si as framework atoms benefits the post-treatment to obtain well-crystalline NES zeolite.

☑ 本文采用水热法制备了(Si,Ge)-IWV和(Si,Ge,Al)-IWV(大孔超笼)沸石，随后通过后合成处理得到(Si,Ge)-NES沸石(中孔笼)。研究发现IWV沸石仅以Ge和Si为骨架原子，有利于后处理得到结晶良好的NES沸石。

10

Article

Luminescent coordination polymers with mixed carboxylate and triazole ligands for rapid detection of chloroprene metabolite

Yue Mao, Zhonghang Chen, Tiankai Sun, Wenyue Cui, Peng Cheng, Wei Shi*

Chin. J. Struct. Chem., 2024, 43, 100353

☑ A three-dimensional Zn-based coordination polymer (1) and a two-dimensional Cd-based coordination polymer (2) were synthesized with mixed ligands of 2,5-furandicarboxylic acid and 1,2,4-triazole and fully characterized. 2 exhibits excellent stability and superior sensing performance for 1H2B and demonstrates good selectivity in presence of main coexisting compounds in urine.

☑  本研究以2,5-呋喃二甲酸和1,2,4-三唑的混合配体合成了三维Zn基配位聚合物 (1) 和二维Cd基配位聚合物 (2)，并进行了充分的表征。结果表明，配位聚合物 2 对1H2B表现出优异的稳定性和传感性能，并在尿液中主要共存化合物的存在下展现了良好的选择性。

11

Article

Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands

Hao Jiang, Yuan-Yuan He, Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu, Chun-Hua Liu, Yin-Shan Meng*, Tao Liu*, Yuan-Yuan Zhu*

Chin. J. Struct. Chem., 2024, 43, 100354

☑ Two bipyridine oxazoline ligands serve as effective antennae for sensitizing lanthanide emissions, with their structural versatility enabling precise tuning of the ³T energy level to modulate luminous capacities and efficiency.

12

Article

Rigid-flexible-ligand-ornamented lanthanide-incorporated selenotungstates and photoluminescence properties

Tiantian Gong, Yanan Chen, Shuo Wang, Miao Wang*, Junwei Zhao*

Chin. J. Struct. Chem., 2024, 43, 100370

☑ Two novel mixed-organic-ligand-ornamented lanthanide incorporated selenotungstates were synthesized and the energy transfer from [B-α-SeW₉O₃₃]^8– to Sm³⁺ ions has been demonstrated by time-resolved spectroscopy.

13

Review

Metallic nanoparticles for visual sensing: Design, mechanism, and application

Bharathi Natarajan, Palanisamy Kannan*, Longhua Guo* 

Chin. J. Struct. Chem., 2024, 43, 100349

☑  Metal nanoparticles such as gold, silver, iron oxide, and cerium oxide were used for the simple and facile colorimetric detection of various biomolecules via changes in different colors.

14

Review

Nitrate-bridged hybrid organic-inorganic perovskites

Yan Cheng, Hai-Quan Yao, Ya-Di Zhang, Chao Shi, Heng-Yun Ye*, Na Wang*

Chin. J. Struct. Chem., 2024, 43, 100358

☑  Nitrate ions can bridge metal ions with larger radii to form perovskite structures. These hybrid perovskites exhibit rich physical properties, including structural phase transition, ferroelectricity, piezoelectricity, piezomagnetism, and luminescence properties.