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Chin. J. Struct. Chem. 第1期共收录15篇文章。内容涉及氢活化与氢加成的协同效应、表面缺陷钝化的化学机制、官能团植入策略改善双折射性能、磷化控制方法在异质结中的应用、双金属催化剂的电化学固氮能力、CoFe合金的双功能氧电催化性能、多重共振热激活延迟荧光材料的结构设计策略以及手性质子纳米材料的定向合成与应用潜力等。
感谢作者、编委与审稿专家的大力支持。敬请各位专家和同行阅读分享与批评指正！
CJSC文章可在Elsevier网站下载全文。
Volume 44, Issue 1
封面文章
上海科技大学刘朋昕研究员，福州大学刘锟隆博士等人——Hydrogen spillover enhances the selective hydrogenation of α, β-unsaturated aldehydes on the Cu–O–Ce interface
在本期封面文章中，上海科技大学刘朋昕研究员，福州大学刘锟隆博士等发现单原子钯活化产生的活性氢物种通过氢溢流可使惰性的二氧化铈变为选择性加氢的催化活性位点。氢溢流产生的氢离子和氢负离子对于不饱和醛的醛基加氢性能优异。该研究报道了一种单原子合金与载体之间的协同效应，为设计选择性催化剂提供了新的思路。
01
News & Views
Lithium-ion rapid transport mechanism and channel design in solid electrolytes
Jia-Hui Li, Jinkai Qiu, Cheng Lian*
Chin. J. Struct. Chem., 2025, 44, 100381
原文链接
https://doi.org/10.1016/j.cjsc.2024.100381
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02
News & Views
Hexavalent iridium catalyst enhances efficiency of hydrogen production
Hong Yin, Zhipeng Yu*
Chin. J. Struct. Chem., 2025, 44, 100382
原文链接
https://doi.org/10.1016/j.cjsc.2024.100382
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03
News & Views
Electrosynthesis of hydroxylamine from earth-abundant small molecules
Wen-Bo Wei, Qi-Long Zhu*
Chin. J. Struct. Chem., 2025, 44, 100383
原文链接
https://doi.org/10.1016/j.cjsc.2024.100383
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04
News & Views
Optimization strategy for rechargeable Zn metal batteries over wide-pH aqueous electrolytes
Chuyuan Lin, Hui Lin, Lingxing Zeng
Chin. J. Struct. Chem., 2025, 44, 100407
原文链接
https://doi.org/10.1016/j.cjsc.2024.100407
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05
News & Views
Rational design of metal-metal hydroxide interface for efficient electrocatalytic oxidation of biomass-derived platform molecules
Yuchen Wang*, Zhenhao Xu, Kai Yan
Chin. J. Struct. Chem., 2025, 44, 100418
原文链接
https://doi.org/10.1016/j.cjsc.2024.100418
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06
Perspective
Improving the electrocatalysts for conversion-type anodes of alkali-ion batteries
Ajay Piriya Vijaya Kumar Saroja, Yuhan Wu*, Yang Xu*
Chin. J. Struct. Chem., 2025, 44, 100408
原文链接
https://doi.org/10.1016/j.cjsc.2024.100408
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07
Short Communication
Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4
Mengjia Luo, Yi Qiu*, Zhengyang Zhou*
Chin. J. Struct. Chem., 2025, 44, 100446
原文链接
https://doi.org/10.1016/j.cjsc.2024.100446
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08
Article
Hydrogen spillover enhances the selective hydrogenation of α,β-unsaturated aldehydes on the Cu–O–Ce interface
Jinyuan Cui, Tingting Yang, Teng Xu, Jin Lin, Kunlong Liu*, Pengxin Liu*
Chin. J. Struct. Chem., 2025, 44, 100438
☑ The synergy between H2-activation on atomically dispersed Pd and H-addition on Cu–O–Ce interfaces guarantees the highly active and selective hydrogenation of several α, β-unsaturated aldehydes via hydrogen spillover.
☑ 原子分散钯上的氢活化与 Cu–O–Ce 界面上的氢加成之间的协同作用保证了通过氢溢出对多种 α、β- 不饱和醛进行高活性和选择性氢化。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100438
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09
Article
In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors
Wenli Xu, Yingzhao Zhang, Rui Wang, Chenyang Liu, Jialin Liu, Xiangyu Huo, Xinying Liu, He Zhang, Jianxu Ding*
Chin. J. Struct. Chem., 2025, 44, 100454
☑ BA2PbI4 is selected to passivate the surface defects of MAPbBr3 SCFs. The addition of BA interacts with MA vacancy through chemical bonding, thus reducing the surface defect density to achieve high performance photodetector.
☑ 选择 BA2PbI4 来钝化 MAPbBr3 SCF 的表面缺陷。添加的 BA 通过化学键与 MA 空位相互作用，从而降低了表面缺陷密度，实现了高性能光电探测器。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100454
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10
Article
From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation
Yong-Fang Shi, Sheng-Hua Zhou, Zuju Ma, Xin-Tao Wu, Hua Lin*, Qi-Long Zhu*
Chin. J. Struct. Chem., 2025, 44, 100455
☑ A functional group implantation strategy was proposed to significantly enhance the birefringent performance by replacing isotropic [S]2– ions in the chalcogenide [Ba3S][GeS4] with anisotropic π-conjugated [CO3]2– groups in oxychalcogenide [Ba3CO3][MS4] (M = Ge and Sn). This implantation of functional groups does not alter the overall structure; however, both optical anisotropy and birefringence are greatly improved.
☑ 为了显著提高双折射性能，我们提出了一种官能团植入策略，即用氧粲化物[Ba3CO3][MS4]（M = Ge 和 Sn）中各向异性的π-共轭[CO3]2–基团取代粲化物[Ba3S][GeS4]中各向同性的[S]2–离子。这种官能团的植入不会改变整体结构，但却大大改善了光学各向异性和双折射。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100455
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11
Article
Interfacial engineering of core/satellite-structured RuP/RuP2 heterojunctions for enhanced pH-universal hydrogen evolution reaction
Lizhang Chen, Yu Fang, Mingxin Pang, Ruoxu Sun, Lin Xu*, Qixing Zhou*, Yawen Tang*
Chin. J. Struct. Chem., 2025, 44, 100461
☑ The neoteric phosphorization-controlled method is reported for the in-situ immobilization of core/satellite-structured RuP/RuP2 heterojunctions onto N,P co-doped porous carbon nanosheets as a high-performance HER electrocatalyst.
☑ 本文报告了一种新的磷化控制方法，用于将核心/卫星结构的 RuP/RuP2 异质结原位固定到 N、P 共掺杂的多孔碳纳米片上，作为一种高性能 HER 电催化剂。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100461
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12
Article
p-d orbital hybridization induced by CuGa2 promotes selective N2 electroreduction
Bin Chen, Chaoyang Zheng, Dehuan Shi, Yi Huang, Renxia Deng, Yang Wei, Zheyuan Liu, Yan Yu*, Shenghong Zhong*
Chin. J. Struct. Chem., 2025, 44, 100468
☑ This study presents a novel bimetallic CuGa2 catalyst, utilizing p-d orbital hybridization to enhance electrochemical nitrogen fixation, achieving 9.82 μg h–1 cm–2 NH3 yield and 38.25% Faradaic efficiency.
☑ 本研究提出了一种新型双金属 CuGa2 催化剂，利用 p-d 轨道杂化技术提高了电化学固氮作用，实现了 9.82 μg h–1 cm–2 的 NH3 产量和 38.25% 的 Faradaic 效率。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100468
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13
Article
Strategic modulation of CoFe sites for advanced bifunctional oxygen electrocatalyst
Juhong Zhou, Hui Zhao, Ping Han, Ziyue Wang, Yan Zhang, Xiaoxia Mao, Konglin Wu*, Shengjue Deng*, Wenxiang He*, Binbin Jiang*
Chin. J. Struct. Chem., 2025, 44, 100470
☑ The CoFe alloy embedded in pyridinic nitrogen enriched N-doped carbon exhibits advanced bifunctional oxygen electrocatalytic activities. The assembled rechargeable Zn-air battery using CoFe/P-NC provides outstanding performances.
☑ 嵌入富含吡啶氮的掺氮碳中的 CoFe 合金具有先进的双功能氧电催化活性。使用 CoFe/P-NC 组装的可充电锌-空气电池性能卓越。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100470
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14
Review
Recent progress in steric modulation of MR-TADF materials and doping concentration independent OLEDs with narrowband emission
Jun-Yi Wang, Jue-Yu Bao, Zheng-Guang Wu*, Zheng-Yin Du, Xunwen Xiao, Xu-Feng Luo*
Chin. J. Struct. Chem., 2025, 44, 100451
☑ This review highlights the structural design strategies of multiple-resonance thermally activated delayed fluorescence (MR-TADF) materials to mitigate π-π stacking through steric modulation. It explores their progress in concentration-independent OLEDs and addresses future challenges, promoting advancements in narrow-emission OLED technologies.
☑ 本综述重点介绍了多重共振热激活延迟荧光(MR-TADF) 材料的结构设计策略，通过立体调制减轻π-π堆叠。报告探讨了他们在与浓度无关的有机发光二极管方面取得的进展，并探讨了未来的挑战，推动了窄发射有机发光二极管技术的进步。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100451
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15
Review
Plasmonic nanocrystals with intrinsic chirality: Biomolecule directed synthesis and applications
Yiming Yang, Lichao Sun*, Qingfeng Zhang*
Chin. J. Struct. Chem., 2025, 44, 100467
☑ Here we review the recent advances in the biomolecule-directed synthesis and geometry control of chiral plasmonic nanomaterials and widen the scope of their potential applications. It is envisioned that these studies will pave the way toward the rational design of chiral plasmonic nanomaterials with desired optical properties for emerging applications.
☑ 该综述回顾了手性质子纳米材料的生物分子定向合成和几何控制方面的最新进展，并拓宽了其潜在的应用范围。预计这些研究将为合理设计具有所需光学特性的手性质子纳米材料铺平道路，从而促进新兴应用。
原文链接
https://doi.org/10.1016/j.cjsc.2024.100467
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往期回顾
2024年第12期目录
CJSC电催化文章集锦
CJSC非线性光学文章集锦
Chin. J. Struct. Chem 分子筛催化专刊
太阳能光催化专刊
