学海汪洋,毓仁作圣。中大化学发轫于 1924 年建校之初,肇基于百端丛集、内外交困之际。更址改制,而弦歌不辍;分合无时,而传承自序。筚路蓝缕,以启山林,一代代化学人秉承为社会福、为邦家光之理想,恪守中山先生“博学、审问、慎思、明辨、笃行”之校训,行远自迩,笃行不怠,守正创新,踵事增华。历经百年,中山大学化学坚持以立德树人为根本任务,融中外思想,育天下英才,致家国多福,为实现中华民族伟大复兴的中国梦而不懈奋斗。
本专辑由高松院士、陈小明院士、苏成勇教授和张伟雄教授担任客座编辑,主要收录中山大学学者和校友等研究人员在药物化学、材料化学、分析化学、有机化学等跨学科多领域的最新研究进展,合辑现已上线,后续将持续收录和更新上线文章。
目前入选的作者包括:王洪根教授、倪兆平教授、欧阳钢锋教授、余丁山教授、潘梅教授、吴丁财教授、匡代彬教授、朱克龙教授、徐飞教授 (西北工业大学)、龙腊生教授(厦门大学)、陈忠宁研究员(中科院福建物构所)、张献明教授 (太原理工大学)、李丹教授 (暨南大学) 等。
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↓↓ 目前入选工作 ↓↓
Stereodivergent atom transfer radical addition of α-functionalized alkyl iodides to alkynes: a strategy for selective synthesis of both E- and Z-iodoalkenes
Ya-Jie Tang, Qi Fan, Xiaoya Li, Qingjiang Li, Biaolin Yin* (尹标林, 华南理工大学) and Honggen Wang* (王洪根, 中山大学)
👉 A photo-redox stereodivergent atom transfer radical addition of α-functionalized alkyl iodides to alkynes allows the selective and efficient synthesis of both E- and Z-iodoalkenes.
Chem. Commun., 2024, 60, 13251-13254
https://doi.org/10.1039/D4CC04948ASynergetic spin crossover and fluorescence in a mononuclear iron(III) complex
Zi-Xuan Fan, Kai-Ting Lian, Pei-Yu Liao, Ze-Yu Ruan, Zhao-Ping Ni* (倪兆平, 中山大学) and Ming-Liang Tong
👉 The synergetic effect between abrupt spin crossover and fluorescence is observed for the first time in an iron(III) complex.
Chem. Commun., 2024, 60, 13227-13230
https://doi.org/10.1039/D4CC05036CSimultaneous production of CO and H2O2 by paired electrolysis coupling CO2 reduction and water oxidation
Jian-Hao Wu, Rong-Jie Guo, Jia-Wei Wang* (王嘉蔚, 中山大学), Fu-Jun Niu* (牛富军, 中山大学), Lie-Jin Guo* (郭烈锦, 中山大学) and Gangfeng Ouyang* (欧阳钢锋, 中山大学)
👉 This work introduces a rare example of CO2R-to-CO coupled with 2e−WOR-to-H2O2, giving a total energy efficiency of 34%.
Chem. Commun., 2024, 60, 12718-12721
https://doi.org/10.1039/D4CC04436CA ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries
Xiaoqi Gong, Yaozheng Pan, Linfeng Zhong, Jiasheng Wang, Fujie Liu, Guangsheng Qi, Jing Li, Cong Liu* (刘聪, 中山大学) and Dingshan Yu* (余丁山, 中山大学)
👉 We develop a novel membrane electrolyte comprising h-BN-doped PEO modified PVDF-HFP-nanofibers with high ionic conductivity (3.3 × 10−4 S cm−1) and Li+ transference number (0.74), endowing solid LiFePO4//Li batteries with excellent cyclability.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC04550EEngineering heterostructured Mo2C/MoS2 catalyst with hydrophilicity/aerophobicity via carbothermal shock for efficient alkaline hydrogen evolution
Hao Xiong, Xinren Zhang, Xu Peng, Dengke Liu, Yimeng Han and Fei Xu* (徐飞, 西北工业大学)
👉 Mo2C/MoS2 heterostructure catalysts with hydrophilicity/aerophobicity are rapidly synthesized via carbothermal shock, demonstrating the accelerating alkaline HER kinetics.
Chem. Commun., 2024, 60, 11112-11115
https://doi.org/10.1039/D4CC03757JEnhancing the performance of molecule-based piezoelectric sensors by optimizing their microstructures
Zheng-Xiao Tang, Bin Wang, Zhi-Rui Li, Zhuo Huang, Hai-Xia Zhao* (赵海霞, 厦门大学), La-Sheng Long* (龙腊生, 厦门大学) and Lan-Sun Zheng
👉 A molecule-based ferroelectric [(CH3)3NCH2CH2Br][GaBr4] (1), with a d33 value of 331 pC N−1, was synthesized. The power density of the 1@S-PDMS piezoelectric sensor, featuring optimized microstructures, is up to 490 μW cm−2.
Chem. Commun., 2024, 60, 18060-18066
https://doi.org/10.1039/D4SC05442CLong-persistent luminescence by host–guest Förster resonance energy transfer
Hui-Li Sun, Qiang-Sheng Zhang, Zhong-Hao Wang, Yan-Ting Huang and Mei Pan* (潘梅, 中山大学)
👉 An unexpected finding of organic afterglow triggered by a paper (cellulose)-matrixed strategy was reported, which offers a novel host–guest afterglow system attributed to the Förster resonance energy transfer mechanism.
Chem. Sci., 2024, 15, 17600-17607
https://doi.org/10.1039/D4SC04746JMolecular brush-based ultrathin polymer electrolytes with stable interfaces for high-voltage large-areal-capacity lithium metal batteries
Rongfeng Liao, Congping Li, Minghong Zhou, Ruliang Liu, Shaohong Liu* (刘绍鸿, 中山大学) and Dingcai Wu* (吴丁财, 中山大学)
👉 An ultrathin polymer electrolyte with superior ionic conductivity and stable electrolyte/electrode interfaces enables a high-loading Li/NCM811 cell with a capacity retention of up to 71% after 400 cycles at a high cut-off voltage of 4.5 V.
Chem. Sci., 2024, Advance Article
https://doi.org/10.1039/D4SC04454AHighly efficient circularly polarized electroluminescence based on chiral manganese(II) complexes
De-Hao Kong, Yue Wu, Cui-Mi Shi, Hao Zeng, Liang-Jin Xu* (徐亮金, 中科院福建物构所) and Zhong-Ning Chen* (陈忠宁, 中科院福建物构所)
👉 Eco-friendly chiral Mn complexes with Binapo ligands show red CPL (glum = 5.1 × 10−3) and efficient (EQE > 4% and gEL = −8.5 × 10−3), outperforming many Pt and Ir-based devices, paving the way for sustainable materials.
Chem. Sci., 2024, 15, 16698-16704
https://doi.org/10.1039/D4SC04748FOptical activity levels of metal centers controlling multi-mode emissions in low-dimensional hybrid metal halides for anti-counterfeiting and information encryption
Qiqiong Ren, Guojun Zhou, Yilin Mao, Nan Zhang, Jian Zhang and Xian-Ming Zhang* (张献明, 太原理工大学)
👉 The optical activity levels of metal centers govern the multi-mode emissions by manipulating the band alignments in hybrid metal halides.
Chem. Sci., 2024, 15, 16536-16545
https://doi.org/10.1039/D4SC05041JBisphosphonium cation based metal halide glass scintillators with tunable melting points
Jian-Bin Luo, Jun-Hua Wei, Zi-Lin He, Jing-Hua Chen, Qing-Peng Peng, Zhi-Zhong Zhang and Dai-Bin Kuang* (匡代彬, 中山大学)
👉 Chain elongation and halogen substitution strategies are employed to synthesize low-melting-point bisphosphonium cation based metal halides, which can be used to fabricate highly stable glass scintillators.
Chem. Sci., 2024, 15, 16338-16346
https://doi.org/10.1039/D4SC04229HAchievement of a giant electromechanical conversion coefficient in a molecule-based ferroelectric
Bin Wang, Zhirui Li, Zhengxiao Tang, Haixia Zhao* (赵海霞, 厦门大学), Lasheng Long* (龙腊生, 厦门大学) and Lansun Zheng
👉 A molecule-based ferroelectric, possessing the highest d33 × g33 values recorded to date, achieves a record power density of 120 μW cm−2 in ferroelectric@PDMS PEGs, offering a viable method to enhance the electromechanical conversion coefficient.
Chem. Sci., 2024, 15, 15192-15197
https://doi.org/10.1039/D4SC04185BA compact chemically driven [2]catenane rotary motor operated through alternate pumping and discharging
Anquan Li, Zhenglin Du, Shilong Zhang, Jialin Xie, Xia Li, Qing Chen, Yisong Tang, Jiawen Chen and Kelong Zhu* (朱克龙, 中山大学)
👉 A compact chemically driven [2]catenane rotary motor was designed for precise 360° unidirectional rotation utilizing a molecular pumping system. It operates in two phases: pumping induces a 180° rotation and discharging resets the motor.
Chem. Sci., 2024, 15, 14721-14725
https://doi.org/10.1039/D4SC04292AA cyclic trinuclear silver complex for photosynthesis of hydrogen peroxide
Ri-Qin Xia, Zhen-Na Liu, Yu-Ying Tang, Xiao Luo, Rong-Jia Wei, Tao Wu, Guo-Hong Ning* and Dan Li* (李丹, 暨南大学)
👉 A BODIPY-based silver cyclic trinuclear complex can be used as a photocatalyst for producing H2O2 either from pure water or from sea water with high photocatalytic activities in the absence of any additives.
Chem. Sci., 2024, 15, 14513-14520
https://doi.org/10.1039/D4SC04098H
同时,为庆祝中山大学百年校庆,2024 年 11 月 30 日 – 12 月 01 日, 英国皇家化学会还将联合中山大学共同举办一届青年学者论坛以示庆贺。论坛主席为中山大学化学学院院长苏成勇教授和暨南大学李丹教授,聚焦“小分子高效转化” ,希望将有机、无机、物化等相关领域的青年学者聚集一堂,深入探讨研究前沿与交叉合作机会。
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