24年11月18日文献情报（5篇）

24年11月18日文献情报

1. 题目: Cascade reservoirs affected chemical compositions of dissolved organic matter and greenhouse gas dynamics in the Lancang River.

文章编号: N24111805
期刊: Science of the Total Environment
作者: Yueting Meng, Jiarui Li, Hongbo Wang, Lei Du, Xiaohui Zhao, Jiaju Liu, Baozhu Pan, Ting Wang
更新时间: 2024-11-18
摘要: Dissolved organic matter (DOM) is an important component in aquatic systems. There has been much debate about the potential effects of cascade reservoirs on the transport and transformation of DOM. Here, through a survey of source to leave-boundary section of Lancang River (LCR) in June and November of 2017-2018, our results revealed that weak spatiotemporal variations were observed for DOC content, whereas DOM parameters were significantly different between natural and reservoir reaches. And DOM showed higher humification degree from allochthonous sources with increasing autochthonous matter in reservoir reach, may due to high particulate organic matter and releasing autochthonous DOM from phytoplankton blooms in the LCR, which can be evidenced by depleted DIC, enriched δ13CDIC and higher BIX. A unique fluorescent fraction (C5) appeared in the reservoir reach and increased along water flow, which was strongly associated with dissolved CO2 and N2O. Meanwhile, BIX value decreased with increasing dam height, hydraulic residence time (HRT), and reservoir capacity, which may promote CH4 production, highlighting variation of DOM compositions in understanding the effect of greenhouse gas (GHG) dynamics in the LCR. The findings were essential for comprehending the influences of cascade reservoirs on carbon cycle, and informed policy development for the sustainable management of transboundary water resources like the LCR.
文章二维码:

2. 题目: Reduction of hexavalent chromium by compost-derived dissolved organic matter.

文章编号: N24111804
期刊: Environmental Science: Processes & Impacts
作者: Chuanghe Miao, Hui Rong, Xiaoqing Wei, Jianying Shang, Hu Zhou, Yizhong Lv
更新时间: 2024-11-18
摘要: Compost-derived dissolved organic matter (DOMC) is a heterogeneous assemblage of different redox-active organic molecules. We hypothesize that DOMC can interact with Cr(VI) and reduce it to Cr(III), thereby influencing the dynamics of Cr(VI) in soil and aquatic environments. Here, DOMC, along with soil humic substances isolated from red soil and black soil, were fractionated into humic acid fractions (i.e., HAC, HAB, and HAR) and fulvic acid fractions (i.e., FAC, FAB, and FAR), respectively. The reduction and interaction between Cr(VI) and the six organic matter fractions were investigated. The results showed that the total Cr(VI) reduction capacity (TRC) of the six organic matter fractions was 26.77-49.34 μM Cr(VI) per mg OM. The TRC of HA fractions was 35.54-49.34 μM Cr(VI) per mg OM, which exceeded that of FA fractions (26.77-31.29 μM Cr(VI) per mg OM). DOMC had a HA/FA ratio of 0.64, which was higher than that of black soil humic substance (0.59) and red soil humic substance (0.20). The sum of the TRC of DOMC was 35.57 μM Cr(VI) per mg OM, which was larger than that of black soil humic substance (32.87 μM Cr(VI) per mg OM) and red soil humic substance (33.01 μM Cr(VI) per mg OM). The TRC was positively correlated with TOC, TN, phenol C, alkyl C, and aromatic C contents and negatively correlated with E2/E3, O-alkyl C, and carboxyl C contents. The reduction of Cr(VI) at pH 6 was negligible, whereas 32-67% Cr(VI) was reduced at pH 2. The Cr(VI) reduction capacities (RC2, RC2, and RC6) at pH 2-6 were positively correlated (R2 > 0.71) with phenol C. Spectral analysis showed that there was no obvious complexation between Cr(VI) and the six organic matter fractions at pH 6, and thus the reduction of Cr(VI) was negligible, but solution pH could affect the accessibility of organic molecules to Cr(VI) and thus influence Cr(VI) reduction.
文章二维码:

3. 题目: The heterogenous molecular characteristics of biomass-pyrogenic smoke dissolved organic matters (BPS-DOMs) binding with PAHs: novel insights from combined analysis of FT-ICR MS and fluorescence variation

文章编号: N24111803
期刊: Journal of Hazardous Materials
作者: Huiying Zhang, Zhigeng Wang, Qin Dai, Jinzhi Ni, Yue Cheng, Ran Wei, Weifeng Chen
更新时间: 2024-11-18
摘要: Biomass-pyrogenic smoke dissolved organic matter (BPS-DOM) can co-deposit with polycyclic aromatic hydrocarbons (PAHs), thereby altering their environmental behavior and fate in surface environments. However, the heterogeneous molecular characteristics of BPS-DOM binding with PAHs remain unclear. This study systematically elucidates the binding characteristics of PAHs (phenanthrene and pyrene), with various molecular compositions in BPS-DOM, utilizing FT-ICR MS and fluorescence variation analysis. CHO compounds in BPS-DOM, characterized by high aromaticity and abundant C=O bonds, significantly enhance PAHs binding by promoting π-π electron donor-acceptor interactions. In contrast, CHON compounds with higher aliphaticity inhibit pyrene binding by competing for binding sites on BPS-DOM. Furthermore, the binding sequence of different fluorescent molecules follows the order of CHO→CHOS→CHON for phenanthrene and CHO→CHON→CHOS for pyrene. This was primarily due to the larger conjugated aromatic structures of CHO compounds, which provide stronger π-π interaction sites for PAHs binding. The difference in binding sequences between phenanthrene and pyrene is primarily attributed to phenanthrene's reliance on π-π electron donor-acceptor interactions induced by -S=O and -N=O, while pyrene binding depended on π-π interactions driven by larger conjugated aromatic structures. These results provide an important theoretical foundation for further understanding the molecular-level interactions between BPS-DOM and PAHs.
文章二维码:

4. 题目: Arsenic Removal using De-oiled Mentha Biomass Biochar: Adsorption Kinetics and the Role of Iron Modification

文章编号: N24111802
期刊: Journal of Cleaner Production
作者: Sampurna Nand, Saroj Kumar, Bhanu Pratap, Divya Dubey, Mariya Naseem, Anju Patel, Siddharth Shukla, Pankaj Kumar Srivastava
更新时间: 2024-11-18
摘要: Arsenic contamination in water threatens millions of people globally, demanding the development of sustainable and effective remediation strategies. This work investigates the removal of As(V) using Fe-modified biochar derived from de-oiled Mentha waste (MMBC). The study aimed to synthesize MMBC and evaluate its adsorption capacity; secondly, to investigate adsorption kinetics; and lastly, to elucidate the governing mechanisms behind the process. Proximate analysis revealed MMBC's stability (low moisture: 6.48%, high fixed carbon: 54.7%) and high adsorption potential (low volatile matter: 9.77%). Characterization techniques (SEM-EDX, XRD, FTIR, TGA) confirmed a desirable porous structure, favourable chemical composition, and surface functionality critical for As(V) adsorption. Importantly, MMBC exhibited a significantly larger surface area providing more active sites (378.08 m² g⁻¹) as compared to the unmodified biochar. Concerning operational conditions, the optimal As(V) removal was achieved at pH 7.5 with a 25 mg/50 mL MMBC dosage in a 24 h contact time. Further, kinetic modelling indicated a pseudo-second-order mechanism, suggesting chemisorption as the dominant process. However, isotherm studies revealed favourable multilayer adsorption, with the Freundlich model best describing the data. The combined effects of MMBC's porosity, functional groups, and Fe modification facilitated both physical and chemical adsorption mechanisms. These findings highlight MMBC's potential as a promising biochar-based adsorbent for efficient As(V) removal from contaminated water for sustainable remediation.
文章二维码:

5. 题目: Integrative application of biochar and bacteria for mitigating antimony toxicity and bio-accessibility in sorghum.

文章编号: N24111801
期刊: Science of the Total Environment
作者: Muhammad Umair Hassan, Huifang Xu, Mansour Ghorbanpour, Yu Yongfang, Binjuan Yang, Quan Zhou, Tahir Abbas Khan, Huang Guoqin
更新时间: 2024-11-18
摘要: Antimony (Sb) toxicity is a serious concern due to its harmful effects on humans and plants. Biochar (BC) has become a popular amendment for remediating soils polluted with metals and metalloids. However, the exact interaction mechanism between BC, microbes, and the remediation of Sb-polluted soils remains unclear. To address this, a study was performed to determine the impacts of maize straw BC and a bacterial strain (Pseudomonas frederiksbergensis: PF) in mitigating the harmful effects of Sb toxicity on sorghum productivity. A pot experiment was set up with the following treatments: control, soil contaminated with Sb (1000 mg kg-1), Sb-contaminated soil + BC (2 %), Sb-contaminated soil + PF, and Sb-contaminated soil + BC (2 %) + PF. Antimony toxicity significantly reduced sorghum biomass and grain yield while increasing hydrogen peroxide (H2O2: 32.63 %), malondialdehyde (MDA: 68.96 %) reducing chlorophyll a (95.65 %) and chlorophyll b synthesis (92 %), increasing Sb accumulation plant parts and decreasing NPK (24.48 %, 8.01 % and 19.24 %) and magnesium availability, soil organic carbon (SOC: 16.36 %), microbial biomass carbon (MBC: 10.80 %) and soil urease (76.31 %) and catalase (130.52 %) activity. The combined application of BC and bacteria enhanced the promoted sorghum biomass and grain production by improving chlorophyll synthesis, antioxidant activity, osmolyte production, nutrient availability, SOC, MBC, soil enzymatic activities and reducing both H2O2 and MDA production. Co-application of BC and bacteria decreased soil Sb concentration by 38.84 % while they decreased Sb concentration in sorghum root, stem, leaves and grains by 54.58 %, 34.15 %, 30.96 % and 54.58 % respectively. The decrease of Sb concentration in soil and plant parts with BC and bacteria application could be attributed to increase in soil pH, SOC, MBC, enzymes activities. Additionally, BC in combination with bacteria also reduced bio-accessible Sb concentration by 83.82 %, and bio-accessibility of Sb by 36.45 % indicating their appreciable potential to produce safer sorghum production in highly polluted Sb soil Therefore, BC and PF can be used together to improve sorghum production and develop environmentally friendly approaches in Sb-contaminated soils.
文章二维码:

更多信息关注“天然有机质研究情报”。

长按二维码识别关注我们