DOI: https://doi.org/10.1016/j.trac.2019.05.002
在SOFC电极研究中,氧空穴含量对电极材料的性质以及整体电池的性能都至关重要,氧空穴含量与材料的导电性、催化性能等密切相关,对氧空穴进行科学表征,有助于加深对材料的理解,从而设计更加高效的电极材料。本论文中系统总结了对空穴的表征方式,推荐阅读本篇综述,在设计以及表征电极材料时选择合适的表征手段。
Abstract
Oxygen vacancy plays an important role in many fields, such as photocatalysis, energy storages, electro-catalysis, which has been widely investigated both by experiment and theoretical calculations. Herein, this review presents the new type and advanced methods to detect the existence of oxygen vacancies in nanomaterials, such as, electron paramagnetic resonance, synchrotron radiation-based X-ray absorption fine structure, X-ray photoelectron spectroscopy and positron annihilation spectroscopy measurements. In addition, we provide some perspectives on the challenge and new direction for future research in oxygen vacancy. We hope that this minireview can offer some useful contributions to the future development of defective nanomaterials for diverse application.