在前四期MOF相关《Science》论文集锦①②③④中，笔者汇总了近十二年来(2013-2024)发表于Science中的42篇MOF相关论文(平均每年3.5篇)。书接上回，本期笔者整理收集了1999-2012十四年间发表于Science杂志中的19篇MOF相关论文，以飨读者！
其中，2012年2篇，2010年4篇，2009/2008年各1篇，2007/2005年各2篇，2004/2003年各1篇，2002年3篇，2001/1999年各1篇，2011/2006/2000年无(欢迎补充)。该19篇论文中，国人/华人学者为第一作者的共有6篇(尚无通讯作者)。研究主题涵盖IRMOF-74设计合成、碳氢化合物分离、气体吸附位点的直接观测、肽基MOFs、超高孔隙度MOFs、多功能团化MOFs、MOF-大环多醚体、高通量ZIFs合成、MIL-88膨胀现象、MIL-100/101合成、迟滞氢吸附、氢气储存、客体依赖的自旋交叉、IRMOFs及甲烷储存、交织穿插MOF、HKUST-1合成等。具体文献汇总如下：
1. Large-Pore
Apertures in a Series of Metal-Organic Frameworks. Science 2012, 336 (6084), 1018-1023.2. Hydrocarbon
separations in a metal-organic framework with open iron (II) coordination
sites. Science 2012, 335 (6076),
1606-1610.3. Direct
Observation and Quantification of CO2 Binding Within an Amine-Functionalized
Nanoporous Solid. Science 2010, 330 (6004), 650-653.4. An adaptable
peptide-based porous material. Science 2010, 329 (5995), 1053-1057.5. Ultrahigh
Porosity in Metal-Organic Frameworks. Science 2010, 329 (5990), 424-428.6. Multiple
Functional Groups of Varying Ratios in Metal-Organic Frameworks. Science 2010, 327 (5967),
846-850.7. Docking
in Metal-Organic Frameworks. Science 2009, 325 (5942), 855-859.8. High-Throughput
Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture. Science 2008, 319 (5865),
939-943.9. Role
of solvent-host interactions that lead to very large swelling of hybrid
frameworks. Science 2007, 315 (5820), 1828-1831.10. Reversible
concerted ligand substitution at alternating metal sites in an extended solid. Science 2007, 315 (5814),
977-980.11. Gas
Adsorption Sites in a Large-Pore Metal-Organic Framework. Science 2005, 309 (5739), 1350-1354.12. A
Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and
Surface Area. Science 2005, 309 (5743), 2040-2042.13. Hysteretic
adsorption and desorption of hydrogen by nanoporous metal-organic frameworks. Science 2004, 306 (5698),
1012-1015.14. Hydrogen
Storage in Microporous Metal-Organic Frameworks. Science 2003, 300 (5622), 1127-1130.15. Formation
of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid. Science 2002, 298 (5602),
2358-2361.16. Guest-Dependent
Spin Crossover in a Nanoporous Molecular Framework Material. Science 2002, 298 (5599),
1762-1765.17. Systematic
design of pore size and functionality in isoreticular MOFs and their
application in methane storage. Science 2002, 295 (5554), 469-472.18. Interwoven
metal-organic framework on a periodic minimal surface with extra-large pores. Science 2001, 291 (5506),
1021-1023.19. A
chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n. Science 1999, 283 (5405),
1148-1150.
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