报告人：Prof. Sven Schneider
Georg-August-University Göttingen
The direct use of N2 for the synthesis of nitrogenous organic products, such as amines, nitriles, or nitro compounds, is still challenging and catalytic protocols remain unknown. The reductive splitting of dinitrogen into transition metal nitrido complexes represents a potential entry towards N2 fixation beyond ammonia.[1] Over the past years, our group examined the mechanisms of chemically, photochemically, and electrochemically driven reductive N2 splitting by group 6 and 7 metal complexes as a starting for the transformation of dinitrogen to nitrogenous products, like organic nitriles (see Figure).[2]
In this presentation, the mechanistic and electronic structure prerequisites for electro- and photochemically driven reductive N2 splitting that is mediated by molecular pincer complexes will be presented, as well as strategies for efficient nitrogen transfer to target molecules.
Sven Schneider is a Professor for Functional Supramolecular Chemistry at the Department of Chemistry, Georg-August University Göttingen in Germany. He has received several prestigious honors and awards throughout his career, including being the Speaker of the Collaborative Research Centre "Pushing Electrons with Protons" since 2024, receiving a European Research Council Consolidator Grant in 2015, being awarded the Chemistry Award of the Lower-Saxony Academy of Sciences in 2010, and participating in the Emmy Noether Program from 2006 to 2012.
