Contents
Preface xxi
Contributors xxiii
1. Fluorous Chemistry: Scope and Definition 1
2. A Personal View of the History of Fluorous Chemistry 5
3. Fluorous Solvents and Related Media 11
4. Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation 24
5. Ponytails: Structural and Electronic Considerations 41
6. Partition Coefficients Involving Fluorous Solvents 56
7. Separations with Fluorous Silica Gel and Related Materials 101
8. Light Fluorous Chemistry—A User´s Guide 128
9. Getting Started in Synthesis: A Tabular Guide to Selected Monofunctional Fluorous Compounds 156
10. Highlights of Applications in Synthesis and Catalysis 175
11. Preparations 366
12. Applications of Fluorous Compounds in Materials Chemistry 478
13. Fluorous Materials for Biomedical Uses 521
14. Fun and Games with Fluorous Chemistry 574
Index 586
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